Here are release details for the US. You can find release details for other countries at the official site, which is listed below:
There are four boxed sets, the first two set for release on 7 November 2006 and the other two due on 12 December 2006. Each set will contain five Bond films, for a total of twenty when all the sets are released.
Volume 1 (Gold Box Set - 7 November): Goldfinger, Diamonds Are Forever, The Man With The Golden Gun, The Living Daylights, and The World Is Not Enough
At Walmart for $60.39
Volume 2 (Blue Box Set - 7 November): Thunderball, The Spy Who Loved Me, A View To A Kill, Licence To Kill, and Die Another Day
At Walmart for $60.39
Volume 3 (Red Box Set - 12 December): From Russia With Love, On Her Majesty’s Secret Service, Live And Let Die, For Your Eyes Only, and GoldenEye
At Walmart for $56.87
Volume 4 (Silver Box Set - 12 December): Dr. No, You Only Live Twice, Moonraker, Octopussy, and Tomorrow Never Dies
At Walmart for $56.87
http://www.walmart.com/search/search...&search_sort=4
Actor Specific Box Sets / Special Collections
According to Play.com, three new James Bond ‘Ultimate Edition’ sets will be released on 27 November 2006:
the Sean Connery, Roger Moore, and Pierce Brosnan box sets.
The Connery set will include all six of his official James Bond films, all seven for the Moore set and all four for the Brosnan set.
Also set for release on 27 November is The Ultimate Golden Triple Pack, which contains: Goldfinger, The Man With The Golden Gun, and GoldenEye.
You can order these thru Amazon.com
Here is the official website for the Ultimate Edition DVDs
http://www.theultimatebond.com/